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Prepare the Chicken: Season the chicken pieces with a little salt and pepper.
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Brown the Chicken: Heat the vegetable oil in a large skillet over medium-high heat. Add the chicken pieces and cook, stirring occasionally, for 5-7 minutes, or until the chicken is browned and cooked through. Remove the chicken from the skillet and set aside.
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Make the Sauce: In the same skillet, add the bourbon, soy sauce, brown sugar, ketchup, rice vinegar, minced garlic, ground ginger, and crushed red pepper flakes (if using). Stir to combine and bring the mixture to a simmer.
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Thicken the Sauce: In a small bowl, mix the cornstarch with the water to create a slurry. Add the slurry to the simmering sauce and stir until the sauce thickens, about 2-3 minutes.
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Combine Chicken and Sauce: Return the cooked chicken to the skillet and toss to coat in the sauce. Cook for an additional 2-3 minutes, or until the chicken is heated through and well-coated with the sauce.
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Garnish and Serve: Garnish with chopped green onions. Serve the bourbon chicken over cooked rice.
